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process has high energy consumption and produces undesirable pollutants.4,5 In the second method (direct conversion method), the conversion is maintained through the use of Na2CO3 or other carbonate sources.2,3,6 The conversion of SrSO4 to SrCO3 in alkali carbonate solution was studied

US3304155A US35156664A US3304155A US 3304155 A US3304155 A US 3304155A US 35156664 A US35156664 A US 35156664A US 3304155 A US3304155 A US 3304155A Authority US United States Prior art keywords barium barium sulfate carbonate process reaction mixture Prior art date 1963-03-28 Legal status (The legal status is an assumption and is not a legal conclusion.

Magnesium sulfate is an inorganic salt with the formula MgSO 4 (H 2 O) x where 0≤x≤7. It is often encountered as the heptahydrate sulfate mineral epsomite (MgSO 4 ·7H 2 O), commonly called Epsom salt.The overall global annual usage in the mid-1970s of the monohydrate was 2.3 million tons, of which the majority was used in agriculture.

perature trend; for example, calcium carbonate shows the inverse trend of increasing water sol-ubility with decreasing temperature. The solu-bility of barium sulfate increases by a factor of two in the temperature range 25°C to 100°C [77° to 212°F] and then decreases by the same magnitude as temperatures approach 200°C [392°F].

system include calcium carbonate, calcium phosphate, calcium sulfate, collo idal silica, metal silicates, etc. However, deposition of BaSO 4 and SrSO 4 on the RO membrane surface is also observed due to incompatibility of sea water containing high sulfate with barium and strontium rich formation water. The long term success of an RO system

strontium carbonate, which contains at least 98% strontium carbonate. The soda ash or direct conversion method produces technical-grade strontium carbonate, containing at least 97% strontium carbonate. The first step in the black ash process involves mixing the crushed and screened celestite with powdered coal. The mixture

The onset of water production coinciding with simultaneous reduction in oil production is a sign of potential scale problems. It is quite possible, particularly with gas wells, to produce water below the limit of detection of surface analysis (nominally 1 or 2%).

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Mixing of two incompatible brines (most commonly formation water rich in cations such as barium, calcium . and/or strontium, mixing with sulfate rich seawater, goes to the precipitation of sulfate ...

Summary. Detection of 0.002μg barium given as barium sulfate or 0.01μg strontium given as strontium sulfate and identification of the two metals in mixtures of the sulfates with limiting proportions of 1 Ba ∶ 250 Sr and 1 Sr ∶ 200 Ba is accomplished by conversion to perchlorate, suitable modification of the rhodizonate test, and combining the latter with a simple separation procedure.

For ionic compounds with limited solubility in water, an equilibrium constant, K sp, can be defined from the ion concentration in water from the equation:. M m A n (s) = mM n+ (aq) + nA m-(aq). where M m A n is the slightly soluble substance and M n+ and A m-are the ions produced in solution by dissosiation of M m A n.. K sp = [M n+] m * [A m-] n. The table below gives calculated values of K ...

The major scales include calcium carbonate, barium sulfate, calcium sulfate, strontium sulfate and sodium chloride. These scales primarily cause the fluid flow impairment and even plug-up of perforations, tubular, valves and surface equipments. The scaling mechanism is very complex where we need to consider thermodynamics, kinetic,

Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive.The metal forms a dark oxide layer when it is exposed to air. Strontium has physical and chemical properties similar to those of its two vertical neighbors in the periodic table, calcium and barium.

Conversion process for strontium sulfate in carbonate rich celestite ores to strontium carbonate using sodium carbonate in an air/vapor-lift loop reactor. US Patent, No: 6159436. Preparation of ...

The Chemistry of Strontium and Barium Scales Robert J. Ferguson and Baron R. Ferguson French Creek Software, Inc. ... Other simple indices use the same approach to predict sulfate and other carbonate scales. The use of these simple indices is not recommended for high TDS water, high ... Repeating the process until corrections are insignificant.

Magnesium carbonate Calcium carbonate Barium carbonate: Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references: Strontium carbonate (SrCO 3 ...

Strontium, like its fellow alkali earths, is highly reactive, and therefore is never found naturally in the form of the pure metal. Its primary mineral deposits are celestite, a strontium sulfate mineral, and strontiantite, a carbonate mineral.

Conversion process for strontium sulfate in carbonate rich celestite ores to strontium carbonate using sodium carbonate in an air/vapor-lift loop reactor. Patent number: 6159436 Abstract: This invention relates to a low energy hydrometallurgical process for the production of strontium carbonate of chemical and glass grade from carbonate rich ...

May 10, 2002· Complete elimination of acid injection in reverse osmosis plants Complete elimination of acid injection in reverse osmosis plants Ning, Robert Y.; Netwig, Jeffrey P. 2002-05-10 00:00:00 Antiscalants with broad activity spectra are available today. When properly chosen, a single antiscalant can efficiently and simultaneously control calcium carbonate, calcium sulfate, strontium sulfate, barium ...

formation water rich in cations such as barium, cal-cium and/or strontium, mixing with sulphate rich seawater, goes to the precipitation of sulphate scales, such as BaSO 4). Table 1. Most Common Oilfield Scales Name Chemical Formula Primary Variables Calcium Carbonate CaCO 3 Partial pressure of CO 2, temperature, total dissolved salts, pH

Carbonate is sometimes referred to as phenolphthalein alkalinity. ... calcium sulfate, barium sulfate, & strontium sulfate. Sulfates also are a food source for sulfate reducing bacteria pH pH is very important in determining calcium carbonate scaling tendencies & the corrosiveness of water. ... Interpretating a Water Analysis(1).doc

Where Does Oilfield Scale Form? The scaling reaction depends on there being adequate concentrations of sulphate ions in the injected seawater and barium, strontium and calcium divalent cations in the formation brine to generate sulphate scale or on there being enough bicarbonate and calcium ions to generate carbonate scale.

Dec 12, 2000· The liquor is transferred to an evaporator for recovering a calcium chloride rich solid and regenerating process water. The strontium sulfate enriched concentrate is washed with fresh water before being fed to the air/vapor-lift loop reactor for conversion to strontium carbonate using a sodium carbonate aqueous medium.

formation water rich in cations such as barium, cal-cium and/or strontium, mixing with sulfate rich sea-water, goes to the precipitation of sulfate scales, such as BaSO 4). Ba2+ (or Sr2+ or Ca2+) + SO 4 2- BaSO 4 (or SrSO 4 or CaSO 4) (2) c) Other fluid incompatibilities include sulfide scale where hydrogen sulfide gas mixes with iron, zinc or
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